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Waterborne polyurethane based on dual crosslinked structure with excellent mechanical properties, water and corrosion resistance

2024年10月12日08:50 来源:无

Researchers found that the introduction of KH-792 as a coupling agent significantly enhances the mechanical properties of the WPU coatings.

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Die Forschung beweist, dass die WPU-Beschichtung mit 3 wt% KH-792 eine au-ergewöhnliche Korrosionsbest-ndigkeit aufweist.  Source: CaptureAndCompose - stock.adobe.com

Due to the increased presence of hydrophilic groups in waterborne polyurethane (WPU) coatings, consequently leading to compromised corrosion resistance and reduced service life. To solve the problem, a series of waterborne polyurethanes were synthesized via internal emulsification using dicyclohexylmethane diisocyanate (HMDI) and polytetrahydrofuran ether diol (PTMG) as the primary raw materials. The triethanolamine (TEOA) was used as a crosslinking agent and corrosion inhibitor, while N- (β-aminoethyl) -γ-aminopropyl trimethyl-(ethyl) oxy-silane (KH-792) was introduced as a coupling agent to establish a system with a dual crosslinking structure.

The crosslinking degree of the double network structure can be adjusted by changing the amount of KH-792. Then the influence of KH-792 content on the performance of SWPU dispersions and film were studied. The research shows that the waterborne polyurethane with a KH-792 content of 3 wt% exhibits exceptional mechanical strength, reaching 34.64 MPa, with only 3.32 % water absorption and an adhesion strength of 2.64 MPa. Furthermore, it exhibited a high impedance modulus (2976.4 Ω/cm2) at low frequencies. Therefore, this compound holds promising potential for application in anti-corrosion coatings field.

Source: Progress in Organic Coatings Volume 197, December 2024, 108784



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